The company said Sunil Duggal, whole-time director and CEO of Hindustan Zinc Ltd, a subsidiary of Vedanta, will take additional charge as an interim CEO of Vedanta Ltd from April 6.
The board has also re-designated Navin Agarwal as executive vice-chairman of the company's board with effect from the close of business hours on Friday.
In a separate statement, Vedanta Ltd said Srinivasan Venkatakrishnan will step down as CEO and the company's director with effect from April 5, 2020, for personal reasons and will rejoin his family in South Africa.
It said the company has appointed Sunil Duggal as interim chief executive officer of the company.
He will report to chairman, the statement said.
On his appointment, Duggal in the statement said, "I am indebted to the company for this appointment. I am confident that at Vedanta, with its strong moorings, I will be able to steer the company through its trajectory of growth and contribute to the economic progress of our country.